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Intramolecular oxidative coupling: I2/TBHP/NaN3-mediated synthesis of benzofuran derivatives.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Xu, Wengang Li, Qingcui Cao, Chuanpeng Zhang, Fanglin Zheng, H. |
| Copyright Year | 2015 |
| Abstract | A novel intramolecular oxidative coupling reaction has been established to prepare benzofuran derivatives via direct C(sp(2))-H functionalization for the formation of C-O bond. This transformation is mediated by I2/TBHP/NaN3 under metal-free conditions and a catalytic amount of NaN3 plays a crucial role in the reaction. Furthermore, the reaction tolerates a broad substrate scope with average to excellent yields. |
| Starting Page | 221 |
| Ending Page | 236 |
| Page Count | 16 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/ob/c5ob00577a/c5ob00577a1.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/getauthorversionpdf/C5OB00577A |
| PubMed reference number | 25946684v1 |
| Alternate Webpage(s) | https://doi.org/10.1039/c5ob00577a |
| DOI | 10.1039/c5ob00577a |
| Journal | Organic & biomolecular chemistry |
| Volume Number | 13 |
| Issue Number | 22 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Benzofurans Oxidative Coupling Sodium Azide |
| Content Type | Text |
| Resource Type | Article |