NDLI: NMR and experimental reinvestigation of the condensation reaction between γ-methylene-α,β-unsaturated aldehydes and propargyl aldehydes.

Content Provider	Semantic Scholar
Author	Riveira, Martín J. Sarotti, Ariel M.
Copyright Year	2018
Abstract	The condensation reaction between a γ-methylene-α,β-unsaturated aldehyde and phenylpropargyl aldehyde was revisited and, guided by extensive DFT calculations of NMR shifts, was found to afford a deconjugative aldol condensation product. In this manner, a simple protocol for the preparation of valuable cross-conjugated oxatrienes was uncovered.
Starting Page	1442
Ending Page	1447
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c7ob03110f
Alternate Webpage(s)	http://www.rsc.org/suppdata/c7/ob/c7ob03110f/c7ob03110f1.pdf
PubMed reference number	29417969
Alternate Webpage(s)	https://doi.org/10.1039/c7ob03110f
Journal	Medline
Volume Number	16
Issue Number	9
Journal	Organic & biomolecular chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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NMR and experimental reinvestigation of the condensation reaction between γ-methylene-α,β-unsaturated aldehydes and propargyl aldehydes.