NDLI: The synthesis and structural characterization of the technetium nitrosyl complexes [TcCl(NO)(SC5H4N)(PPh3)2] and [Tc(NO)(SC5H4N)2(PPh3)].

Content Provider	Semantic Scholar
Author	Nicholson, Terrence Mahmood, Ashfaq Muller, Peter A. Davison, Alan Storm-Blanchard, Shannon Jones, Alun Gwynne
Copyright Year	2011
Abstract	The reaction of the Tc(I) complex [Tc(NO)Cl2(HOMe)(PPh3)2] with stoichiometric amounts of 2-mercatopyridine and a proton scavenger yields [Tc(NO)Cl(Spy)(PPh3)2] or [Tc(NO)(Spy)2(PPh3)], depending upon quantities of ligands employed. These two complexes have been structurally characterized. The small bite angles of the bidentate mercaptopyridine ligands cause significant deviation from octahedral coordination geometry.
Starting Page	484
Ending Page	486
Page Count	3
File Format	PDF HTM / HTML
DOI	10.1016/j.ica.2010.09.025
PubMed reference number	23750048
Journal	Medline
Volume Number	365
Issue Number	1
Alternate Webpage(s)	http://web.mit.edu/pmueller/www/own_papers/nicholson_etal_2011.pdf
Alternate Webpage(s)	https://doi.org/10.1016/j.ica.2010.09.025
Journal	Inorganica chimica acta
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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The synthesis and structural characterization of the technetium nitrosyl complexes [TcCl(NO)(SC5H4N)(PPh3)2] and [Tc(NO)(SC5H4N)2(PPh3)].