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Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdo(V,VI)phosphate hexahydrate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Hao, Lujiang Liu, Tongjun Chen, Jiangkui Zhang, Xiaofei |
| Copyright Year | 2010 |
| Abstract | The hydro-thermally prepared title compound, [Ni(C(8)H(7)N(3))(3)](2)[PMo(12)O(40)]·6H(2)O, is a member of the isotypic series [(M(C(8)H(7)N(3))(3)](2)[PMo(12)O(40)]·6H(2)O where M is Mn, Cd, and Fe. The Ni(2+) cation is in a distorted octa-hedral environment, coordinated by six N atoms from three chelating 3-(2-pyrid-yl)-1H-pyrazole ligands. In the one-electron reduced heteropolyanion, two O atoms of the central PO(4) group ( symmetry) are equally disordered about an inversion centre. N-H⋯O and O-H⋯O hydrogen bonds contribute to the crystal packing. Compared with the isotypic structures, the main difference is related with the M-N bond lengths, whereas all other bond lengths, angles and the hydrogen-bonding motifs are very similar. |
| Starting Page | m319 |
| Ending Page | m320 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 21580258v1 |
| DOI | 10.1107/s1600536810005945 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 66 |
| Alternate Webpage(s) | http://journals.iucr.org/e/issues/2010/03/00/wm2306/wm2306.pdf |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/3f/9c/e-66-0m319.PMC2983742.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536810005945 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Cations Chelating Activity Iron Ligands Pyschological Bonding newton octa-arginine peptide pyrazole |
| Content Type | Text |
| Resource Type | Article |
