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Properties of 0.96(Bi0.5Na0.5)TiO3-(0.04-x)BaTiO3-xLiNbO3 Lead-Free Piezoceramics Near Morphotropic Phase Boundary
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Yating Yang, Ying Li Wang, Yiping Chen, Jing |
| Copyright Year | 2015 |
| Abstract | Abstract The structure, dielectric and piezoelectric properties of 0.96(Bi0.5Na0.5)TiO3-(0.04-x)BaTiO3-xLiNbO3 (x = 0, 0.01, 0.02, 0.03, 0.04) ceramics were investigated by a conventional solid-state reaction method. All compositions show a single perovskite structure without any second phases. It was ascertained that the morphotropic phase boundary (MPB) of ferroelectric rhombohedral and relaxor tetragonal lies in the range of 0.02 ≤ x ≤ 0.04 at room temperature. As a result, the MPB compositions show improved properties; the saturated polarization, remnant polarization and coercive field are 43.7 μC/cm2, 38.7 μC/cm2 and 48.7 kV/cm for x = 0.02 and 43 μC/cm2, 37.9 μC/cm2 and 47 kV/cm for x = 0.03, respectively. The maximum of piezoelectric constant d33 (124pC/N) was obtained for the ceramic with x = 0.03, which was located at the MPB region. Our results do not only supplement for BNT-based lead-free piezoelectric ceramics but also provide a way to develop new high-performance Pb-free piezoceramics. |
| Starting Page | 207 |
| Ending Page | 212 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1515/ehs-2014-0057 |
| Volume Number | 2 |
| Alternate Webpage(s) | https://www.degruyter.com/downloadpdf/j/ehs.2015.2.issue-3-4/ehs-2014-0057/ehs-2014-0057.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |