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Cobalt nanoparticles encapsulated in nitrogen-doped carbon as a bifunctional catalyst for water electrolysis
| Content Provider | Semantic Scholar |
|---|---|
| Author | Wang, Jing Gao, Dunfeng Wang, Guoxiong Miao, Shu Ting Wu, Haihua Li, Jiayuan Bao, Xinhe |
| Copyright Year | 2014 |
| Abstract | The hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are important electrocatalytic processes in water electrolyzers. Identifying efficient non-precious metal catalysts for HER and OER remains a great challenge for applications in different kinds of electrolyzers. Herein, we report that cobalt nanoparticles encapsulated in nitrogen-doped carbon (Co@N-C) show high activity and durability for HER in a wide pH range and for OER in alkaline medium as a bifunctional catalyst. The HER and OER activities of Co@N-C are higher than those of multiwall carbon nanotube and iron nanoparticles encapsulated in nitrogen-doped carbon with a similar content of nitrogen. Electrolyzer prototypes using Nafion NRE-212 as electrolyte membrane and Co@N-C as cathode or anode catalyst are constructed, showing potential practical applications in water splitting. |
| Starting Page | 20067 |
| Ending Page | 20074 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C4TA04337E |
| Volume Number | 2 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ta/c4/c4ta04337e/c4ta04337e1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C4TA04337E |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |