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Selective sensing of 2,4,6-trinitrophenol (TNP) in aqueous media with "aggregation-induced emission enhancement" (AIEE)-active iridium(iii) complexes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Che, Weilong Li, Guangfu Liu, Xingman Shao, Kuizhan Zhu, Dongxia Su, Zhongmin Bryce, Martin R. |
| Copyright Year | 2018 |
| Abstract | A series of new phosphorescent cyclometalated iridium(iii) complexes which possess aggregation-induced emission enhancement (AIEE) detect 2,4,6-trinitrophenol (TNP) selectively with high quenching constants in aqueous media. The sensing mechanism was systematically investigated by mass spectrometry, 1H and 19F NMR spectroscopy. X-ray crystal structure analysis reveals an O-HO interaction between TNP and the ancillary ligand which explains the high selectivity for TNP compared to other nitro-aromatics. |
| Starting Page | 1730 |
| Ending Page | 1733 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c7cc08832a |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c7/cc/c7cc08832a/c7cc08832a1.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2018/cc/c7cc08832a |
| Alternate Webpage(s) | http://dro.dur.ac.uk/23828/3/23828.pdf?DDD7+DDC110+dch0mrb+nvpw35= |
| PubMed reference number | 29376527 |
| Alternate Webpage(s) | https://doi.org/10.1039/c7cc08832a |
| Journal | Medline |
| Volume Number | 54 |
| Issue Number | 14 |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
