NDLI: Ru(ii)-Catalyzed spirocyclization of aryl N-sulfonyl ketimines with aryl isocyanates through an aromatic C-H bond activation.

Content Provider	Semantic Scholar
Author	Nagarjuna Reddy K. Subhadra U. Sridhar B. Subba Reddy B. V.
Copyright Year	2018
Abstract	A novel one-pot strategy has been developed for the construction of spiro-isoindolinone-benzosultams through a Ru(ii)-catalyzed sequential C-C and C-N bond formation. This method is highly atom-economical and compatible with a wide range of substituents. This is the first report on the spirocyclization of 3-aryl N-sulfonyl ketimines with aryl isocyanates to produce highly rigid and pharmaceutically relevant spirocycles through a C-H bond activation.
Starting Page	2522
Ending Page	2526
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1039/C7OB03198J
PubMed reference number	29565426
Journal	Medline
Volume Number	16
Issue Number	14
Alternate Webpage(s)	http://www.rsc.org/suppdata/c7/ob/c7ob03198j/c7ob03198j1.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C7OB03198J
Journal	Organic & biomolecular chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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Ru(ii)-Catalyzed spirocyclization of aryl N-sulfonyl ketimines with aryl isocyanates through an aromatic C-H bond activation.