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Practical P-Chiral Phosphane Ligand for Rh-Catalyzed Asymmetric Hydrogenation
| Content Provider | Semantic Scholar |
|---|---|
| Author | Liu, Duan Zhang, Xumu |
| Copyright Year | 2005 |
| Abstract | A highly electron-donating and conformationally rigid P-chiral bis(trialkylphospholane) ligand 2 (DuanPhos) has been prepared in both enantiomeric forms through a concise syn-thesis. Rh-2 complex has exhibited remarkably high enantio-selectivities (up to >99% ee) and reactivities (up to 10,000 TON) for the hydrogenation of a wide variety of functionalized prochiral alkenes (5 different types), which provides a very practical catalytic system for the preparation of various synthetically useful chiral compounds. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) |
| Starting Page | 646 |
| Ending Page | 649 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/ejoc.200400690 |
| Alternate Webpage(s) | http://research.chem.psu.edu/xzgroup/Assets/publicatioin/EJOC-2005-646.pdf |
| Alternate Webpage(s) | https://doi.org/10.1002/ejoc.200400690 |
| Volume Number | 2005 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |