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Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water|nitrobenzene interface
| Content Provider | Semantic Scholar |
|---|---|
| Author | Gulaboski, Rubin Riedl, Kai Scholz, Fritz |
| Copyright Year | 2003 |
| Abstract | The previously introduced three-phase electrode technique was used to determine the Gibbs energies of transfer of ClO3−, BrO3−, IO3−, IO4−, OCN−, SeCN−, CN−, N3−, halogen substituted acetate anions Z3−nCHnCOO− (Z = F,Cl,Br,I), and cycloalkyl carboxylate anions ((CH2)nCOO−, n = 3,…,7) at the water|nitrobenzene interface. Whereas the data for the small inorganic ions can easily be understood in terms of ion-dipole interactions, the data of the organic ions need consideration of charge delocalisation and its effect on the enthalpy and entropy of solvation. |
| Starting Page | 1284 |
| Ending Page | 1289 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/B210356G |
| Volume Number | 5 |
| Alternate Webpage(s) | http://eprints.ugd.edu.mk/164/1/__ugd.edu.mk_private_UserFiles_rubin.gulaboski_Desktop_GULABOSKI-MY%20pdf%20PUBLICATIONS_PCCP%20paper-2003.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/B210356G |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
