NDLI: Chlorido(η4-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I)

Content Provider	Semantic Scholar
Author	Choate, Michelle M. Peters, R. Gregory Baughman, Russell G.
Copyright Year	2010
Abstract	The title structure,[IrCl(C(8)H(12))(C(14)H(10)F(5)P)], reveals that (C(2)F(5))PPh(2) (penta-fluoro-ethyl-diphenyl-phosphane or pfepp) disrupts the iridium dimer [(cod)IrCl](2) (cod = cyclo-octa-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (cod)Ir(pfepp)Cl with the Ir(I) atom in a distorted square-planar coordination environment. The structure deviates very little from the Ir(I)-triphenyl-phosphine analog, although a significantly (∼20σ) shorter Ir-P bond is noted for the title compound.
Starting Page	m72
Ending Page	m72
Page Count	1
File Format	PDF HTM / HTML
DOI	10.1107/S160053681005141X
PubMed reference number	21522590
Journal	Medline
Volume Number	67
Alternate Webpage(s)	http://ftp.ncbi.nlm.nih.gov/pub/pmc/9e/40/e-67-00m72.PMC3050217.pdf
Alternate Webpage(s)	https://doi.org/10.1107/S160053681005141X
Journal	Acta crystallographica. Section E, Structure reports online
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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