NDLI: A new selective approach to 1,1-bis(silyl)-2-arylethenes and 1,1-bis(silyl)-1,3-butadienes via sequential silylative coupling-Heck coupling reactions.

Content Provider	Semantic Scholar
Author	Pawluć, Piotr Hreczycho, Grzegorz Marciniec, Bogdan
Copyright Year	2006
Abstract	A novel selective route to 1,1-bis(silyl)-1-alkenes has been developed. Sequential one-pot silylative coupling exo-cyclization of 1,2-bis(dimethylvinylsiloxy)ethane followed by the reaction with Grignard reagents leads to the desired 1,1-bis(silyl)ethenes, which are then efficiently coupled in the presence of silver nitrate and palladium acetate with aryl or alkenyl idodides to give the corresponding 1,1-bis(silyl)-2-arylethenes or 1,1,4-trisubstituted 1,3-butadienes with high yield.
File Format	PDF HTM / HTML
DOI	10.1021/jo0616254
PubMed reference number	17064058
Journal	Medline
Volume Number	71
Issue Number	22
Alternate Webpage(s)	http://krastsvetmet.com/images/catalog/pmc/articles/Pd-acetate-3.pdf
Journal	The Journal of organic chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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