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Development of Homogeneous Hydrogenation of Carbon Dioxide to Formate Catalyzed by Copper Complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Watari, Ryo Kayaki, Yoshihito Hirano, Shin-Ichi Matsumoto, Norio Ikariya, Takao |
| Copyright Year | 2017 |
| Abstract | Abstract Hydrogenation of CO 2 promoted by heterogeneous metal catalysts has found commercial applications. Furthermore, homogeneous catalysts based on transition metal complexes have also been demonstrated to be useful in the CO 2 conversion to formate under relatively mild reaction conditions. In the course of our study aimed to uncover the availability of copper complexes, we focused on the ligand acceleration effect on the hydrogenation reaction. Improved formate yield and catalytic activity were obtained by adding selected bisoxazoline ligands to a copper catalyst system. The results presented here open up the possibility to develop efficient copper catalysts based on appropriate ligand design. |
| Starting Page | 7150 |
| Ending Page | 7153 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/j.egypro.2017.03.1877 |
| Volume Number | 114 |
| Alternate Webpage(s) | https://az659834.vo.msecnd.net/eventsairwesteuprod/production-ieaghg-public/1af7ab5147a9413d9354cc55ef3fc797 |
| Alternate Webpage(s) | https://doi.org/10.1016/j.egypro.2017.03.1877 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
