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Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Wu, Xinxin Meng, Chunna Yuan, Xiaoqian Jia, Xiaotong Qian, Xuhong Ye, Jinxing |
| Copyright Year | 2015 |
| Abstract | We report herein an efficient, general and green method for decarboxylative fluorination of aliphatic carboxylic acids. By using a transition-metal-free, organocatalytic photoredox system, the reaction of various aliphatic carboxylic acids with the Selectfluor reagent afforded the corresponding alkyl fluorides in satisfactory yields under visible light irradiation at room temperature. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c5cc04527d |
| PubMed reference number | 26111079 |
| Journal | Medline |
| Volume Number | 51 |
| Issue Number | 59 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/cc/c5cc04527d/c5cc04527d1.pdf |
| Alternate Webpage(s) | http://pubs.rsc.org/en/content/getauthorversionpdf/C5CC04527D |
| Alternate Webpage(s) | https://doi.org/10.1039/c5cc04527d |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |