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On the structure and dynamics of water in AICI3 solutions from H, 0, 17 0, and 27 AI nuclear magnetic relaxation
| Content Provider | Semantic Scholar |
|---|---|
| Author | Maarel, Jasper Van Der Boer, H. W. De Bleijser, J. De Bedeaux, Dick Leyte, Jaap C. |
| Copyright Year | 1987 |
| Abstract | The relaxation rates of 27Al, H, D, 170, and the relaxation rate ofH due to dipolar coupling to 170 were obtained in a series of aqueous AlC13 solutions. From these data conclusions are reached about bulk water dynamics, the O-H bond distance, and the order within the Al3+ hydration shell. The bulk water dynamics is interpreted by a hydrodynamical model. For comparison viscosity data are presented. It is found that the change in the O-H distance of water molecules adjacent to Al3+ is significant and in agreement with reported theoretical results. The destruction of order within the A1 + hexaquo complex with increasing concentration is indicated. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://www.physics.nus.edu.sg/~bcf/publications/JCP_86_3373_1987.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
