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Ultrafine Sn nanocrystals in a hierarchically porous N-doped carbon for lithium ion batteries
Content Provider | Semantic Scholar |
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Author | Chang, Xinghua Wang, Teng Liu, Zhi-Liang Zheng, Xinyao Zheng, Jie Li, Xingguo |
Copyright Year | 2017 |
Abstract | We report a simple method of preparing a high performance, Sn-based anode material for lithium ion batteries (LIBs). Adding H2O2 to an aqueous solution containing Sn2+ and aniline results in simultaneous polymerization of aniline and oxidation of Sn2+ to SnO2, leading to a homogeneous composite of polyaniline and SnO2. Hydrogen thermal reduction of the above composite yields N-doped carbon with hierarchical porosity and homogeneously distributed, ultrafine Sn particles. The nanocomposite exhibits excellent performance as an anode material for lithium ion batteries, showing a high reversible specific capacity of 788 mAh·g−1 at a current density of 100 mA·g−1 after 300 cycles and very good stability up to 5,000 mA·g−1. The simple preparation method combined with the good electrochemical performance is highly promising to promote the application of Sn based anode materials. |
Starting Page | 1950 |
Ending Page | 1958 |
Page Count | 9 |
File Format | PDF HTM / HTML |
DOI | 10.1007/s12274-016-1381-6 |
Volume Number | 10 |
Alternate Webpage(s) | https://static-content.springer.com/esm/art:10.1007%2Fs12274-016-1381-6/MediaObjects/12274_2016_1381_MOESM1_ESM.pdf |
Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1007/s12274-016-1381-6 |
Alternate Webpage(s) | https://doi.org/10.1007/s12274-016-1381-6 |
Journal | Nano Research |
Language | English |
Access Restriction | Open |
Content Type | Text |
Resource Type | Article |