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Glass wool: a novel support for heterogeneous catalysis† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc02115e
| Content Provider | Semantic Scholar |
|---|---|
| Author | Elhage, Ayda Wang, Bowen Marina, Nancy Marin, M. Luisa Cruz, Menandro Lanterna, Anabel E. Scaiano, Juan C. |
| Copyright Year | 2018 |
| Abstract | Heterogeneous catalysis presents significant advantages over homogeneous catalysis such as ease of separation and reuse of the catalyst. Here we show that a very inexpensive, manageable and widely available material - glass wool - can act as a catalyst support for a number of different reactions. Different metal and metal oxide nanoparticles, based on Pd, Co, Cu, Au and Ru, were deposited on glass wool and used as heterogeneous catalysts for a variety of thermal and photochemical organic reactions including reductive de-halogenation of aryl halides, reduction of nitrobenzene, Csp3-Csp3 couplings, N-C heterocycloadditions (click chemistry) and Csp-Csp2 couplings (Sonogashira couplings). The use of glass wool as a catalyst support for important organic reactions, particularly C-C couplings, opens the opportunity to develop economical heterogeneous catalysts with excellent potential for flow photo-chemistry application. |
| Starting Page | 6844 |
| Ending Page | 6852 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c8sc02115e |
| PubMed reference number | 30310617 |
| Journal | Medline |
| Volume Number | 9 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c8/sc/c8sc02115e/c8sc02115e1.pdf |
| Alternate Webpage(s) | https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/9e/ab/SC-009-C8SC02115E.PMC6114997.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c8sc02115e |
| Journal | Chemical science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |