NDLI: Mononuclear and Mixed-Metal Dimethyltin Pacman Complexes of a Schiff-Base Pyrrole Macrocycle

Content Provider	Semantic Scholar
Author	Leeland, James W. Slawin, Alexandra M. Z. Love, Jason B.
Copyright Year	2010
Abstract	The synthesis of the dialkyltin complex [SnMe2(H2L)] of an octadentate Schiff-base pyrrole macrocycle is described in which the gross Pacman geometry enforces structural discrimination between the two methyl groups. The presence of the metal-free compartment engenders the formation of mixed-metal Sn−Fe and Sn−Zn complexes in which the macrocyclic cleft has distorted considerably upon the introduction of the transition metal cation.
Starting Page	714
Ending Page	716
Page Count	3
File Format	PDF HTM / HTML
DOI	10.1021/om901081h
Volume Number	29
Alternate Webpage(s)	https://www.research.ed.ac.uk/portal/files/10854945/Mononuclear_and_mixed_metal_dimethyltin_Pacman_complexes_of_a_Schiff_base_pyrrole_macrocycle_1.pdf
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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