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Enhanced enantioselectivity of 3-methylcyclohexanone by mixed diol host compounds.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Nassimbeni, Luigi R. Curtin, T. |
| Copyright Year | 2012 |
| Abstract | 3-Methylcyclohexanone is only partially resolved by crystallisation with a chiral diol host compound (ee 40%), but when recrystallised from an equimolar mixture of the chiral diol host and a similar but achiral host we obtain complete resolution. The latter host acts as a nucleation inhibitor and the enhanced resolution is attributed to kinetic effects. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c2cc34118b |
| PubMed reference number | 22801591 |
| Journal | Medline |
| Volume Number | 48 |
| Issue Number | 68 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/c2/c2cc34118b/c2cc34118b.pdf |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |