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Energetics of intermolecular HONO formation in condensed-phase octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Lewis, James P. |
| Copyright Year | 2003 |
| Abstract | Abstract We present preliminary work on the formation of HONO in condensed-phase HMX for the three pure polymorphic phases. Our results show that the energetics of the intermolecular hydrogen transfer (to form HONO on an adjacent molecule) is more favorable in δ-HMX than in α-HMX and β-HMX. The energetics of this intermolecular hydrogen transfer process follow the same trends of HMX sensitivity, where δ-HMX is found to be more sensitive to explosion compared to β-HMX. |
| Starting Page | 588 |
| Ending Page | 593 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/S0009-2614(03)00309-9 |
| Alternate Webpage(s) | http://www.sci.utah.edu/publications/Lew2003a/2003_Lewis_Condensed-Phase_HMX.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/S0009-2614%2803%2900309-9 |
| Volume Number | 371 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |