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An electron transfer series of octahedral chromium complexes containing a redox non-innocent α-diimine ligand.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Shen, Jingmei Yap, Glenn P. A. Barker, William E. V. Geiger, William E. Theopold, Klaus H. |
| Copyright Year | 2014 |
| Abstract | An electron-transfer series of octahedral α-diimine complexes [((H)L(Cy))3Cr](n+)(BARF)n (n = 2, 1, 0) has been synthesized and crystallographically characterized. Cyclic voltammetry indicated additional formation of [((H)L(Cy))3Cr](3+). The molecular structures suggested that all redox processes were ligand-based. Magnetic moments were consistent with spin ground states of S = 0 for [(H)L(Cy)3Cr](0), S = 1/2 for [(H)L(Cy)3Cr](+1), and S = 1 for [(H)L(Cy)3Cr](+2). The experimental data is consistent with chromium maintaining the +III oxidation state throughout, while being coordinated by varying numbers of neutral diimines ((H)L(Cy)) and diimine radical anions ((H)L(Cy)˙(-)). |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c4cc03332a |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2014/cc/c4cc03332a?page=search |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/c4/c4cc03332a/c4cc03332a1.pdf |
| Alternate Webpage(s) | http://pubs.rsc.org/en/content/articlepdf/2014/cc/c4cc03332a |
| Alternate Webpage(s) | https://pubs.rsc.org/en/Content/ArticlePDF/2014/CC/C4CC03332A |
| PubMed reference number | 25073609 |
| Alternate Webpage(s) | https://doi.org/10.1039/c4cc03332a |
| Journal | Medline |
| Volume Number | 50 |
| Issue Number | 73 |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
