Hydrothermal Syntheses, Crystal Structures, and Luminescent Properties of Two MnII Coordination Polymers: From Two-Fold Interpenetrated pcu Topological Net to Polycatenated 2D+2D→3D Framework

Content Provider	Semantic Scholar
Author	Liu, Wenlong Wu, Mengqiang Wang, Xueying Wang, Wei Hau Liu, Dayu Wang, Bing Bing
Copyright Year	2014
Abstract	Using a hydrothermal synthesis, the self-assembly of MnII ions and 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene with two dicarboxylate ligands, 2-nitrobenzene-1,4-dicarboxylic acid (2-H2ata) and 5-methylbenzene-1,3-dicarboxylic acid (5-CH3-H2ip) constructed two interesting coordination polymers: [Mn(2-ata)(bimb)]n (1) and {[Mn(5-CH3-ip)(bimb)1.5]·2H2O}n (2), where bimb refers to 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene. Their structures were determined by single-crystal X-ray diffraction, elemental analysis, and infrared spectroscopy. Complex 1 exhibits a 2-fold interpenetrated pcu net. Complex 2 shows an unusual polycatenated 2D+2D→3D framework. In addition, the solid-state photoluminescent properties of 1 and 2 were investigated at room temperature.
Starting Page	322
Ending Page	326
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1071/CH14092
Alternate Webpage(s)	http://www.publish.csiro.au/ch/acc/CH14092/CH14092_AC.pdf
Alternate Webpage(s)	https://doi.org/10.1071/CH14092
Volume Number	68
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article