NDLI: Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites.

Content Provider	Semantic Scholar
Author	Hou, Chaodong Ren, Yunlai Lang, Rui Hu, Xiao-Xue Xia, Chun-Gu Li, Fuwei
Copyright Year	2012
Abstract	The first Pd-catalyzed direct phosphonation of azoles with dialkyl phosphites has been achieved without addition of base or acid. This method involves the oxidative cleavage of C-H and P(O)-H bonds and represents an atom-efficiency alternative to the classical phosphonation of Ar-X. A Pd(II)/Pd(IV) mechanism has been studied and proposed.
File Format	PDF HTM / HTML
DOI	10.1039/c2cc30429e
PubMed reference number	22517113
Journal	Medline
Volume Number	48
Issue Number	42
Alternate Webpage(s)	http://www.rsc.org/suppdata/cc/c2/c2cc30429e/c2cc30429e.pdf
Journal	Chemical communications
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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