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Palladium-catalyzed oxidative annulation of in situ generated enones to pyrroles: a concise route to functionalized indoles
| Content Provider | Semantic Scholar |
|---|---|
| Author | Guo, Tenglong Jiang, Quanbin Yu, Zhengkun |
| Copyright Year | 2015 |
| Abstract | Palladium(II)-catalyzed, copper(II)-mediated indole synthesis was achieved from the reactions of N-substituted simple pyrroles with enones generated in situ from 3-chloropropiophenones. A benzene ring was thus constructed onto a pyrrole backbone, affording substituted indole derivatives. A domino dehydrochlorination/C–H olefination /Diels–Alder cycloaddition/dehydrogenative aromatization sequence was established as the reaction pathway. The present methodology provides a concise route to highly functionalized indole derivatives. |
| Starting Page | 1361 |
| Ending Page | 1365 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5QO00203F |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2016/qo/c6qo90004f |
| Alternate Webpage(s) | http://www.omcat.dicp.ac.cn/pdf/130_ocf-2015.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5QO00203F |
| Volume Number | 2 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
