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Entropy-controlled supramolecular photochirogenesis: enantiodifferentiating Z-E photoisomerization of cyclooctene included and sensitized by permethylated 6-O-benzoyl-beta-cyclodextrin.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Fukuhara, Gaku Mori, Tadashi Wada, Takehiko Inoue, Yoshihisa |
| Copyright Year | 2005 |
| Abstract | In contrast to the photosensitization with a non-methylated analogue, supramolecular photochirogenesis with a novel permethylated mono(6-O-benzoyl)-beta-cyclodextrin exhibited a critical dependence of the product's enantiomeric excess upon temperature, and possessed a large differential entropy of activation (-11 J K(-1) mol(-1)) for which the flexible host skeleton is likely to be responsible. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/b504948b |
| PubMed reference number | 16100602 |
| Journal | Medline |
| Volume Number | 33 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/b5/b504948b/b504948b.pdf |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |