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Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zou, You‐ Quan Chakraborty, Subrata Nerush, Alexander Oren, Dror Diskin-Posner, Yael Ben-David, Yehoshoa Milstein, David |
| Copyright Year | 2018 |
| Abstract | Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal-ligand cooperation of the manganese pincer complex, is proposed based on NMR studies and relevant stoichiometric reactions. |
| Starting Page | 8014 |
| Ending Page | 8019 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/acscatal.8b02902 |
| Alternate Webpage(s) | http://www.weizmann.ac.il/Organic_Chemistry/milstein/sites/Organic_Chemistry.milstein/files/uploads/just_accepted_amide_h2_0.pdf |
| PubMed reference number | 31080688 |
| Alternate Webpage(s) | https://doi.org/10.1021/acscatal.8b02902 |
| Journal | Medline |
| Volume Number | 8 |
| Journal | ACS catalysis |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |