N-Alkyl-p-nitroanilines: impact of alkyl chain length on crystal structures and optical SHG

Content Provider	Semantic Scholar
Author	Gangopadhyay, Palash Rao, Soma Venugopal Rao, Desirazu N. Radhakrishnan, T. P.
Copyright Year	1999
Abstract	N-Alkyl-p-nitroanilines from the propyl to the octyl derivative are synthesised and characterised. Powder SHG studies show that the butyl derivative alone is active, in agreement with earlier observations. Crystal structures of the propyl, butyl and pentyl derivatives are determined; the propyl and pentyl derivatives belong to the centrosymmetric space groups P1 and P2 1 /1v\c respectively and the butyl derivative to the noncentrosymmetric P2 1 2 1 2 1 space group. Detailed analysis of these structures provides insight into the critical role of the alkyl chain length in the formation of centrosymmetric or noncentrosymmetric crystal lattices. The utility of alkyl chain length as a crystal design element for quadratic NLO materials is noted.
Starting Page	1699
Ending Page	1705
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1039/A901591D
Alternate Webpage(s)	http://acrhem.org/download/6.pdf
Alternate Webpage(s)	https://doi.org/10.1039/A901591D
Volume Number	9
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article