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Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zaitsev, Kirill V. Karlov, Sergey S. Zaitseva, Galina S. Lermontova, Elmira Kh. Churakov, Andrei V. |
| Copyright Year | 2013 |
| Abstract | In the title compound, [Ti2(C16H14N2O2)2O2]·2CHCl3, the Ti(IV) atom in the centrosymmetric complex has a distorted octa-hedral N2O4 coordination environment and is linked via two μ2-oxido bridges into a dinuclear centrosymmetric com-plex, with a Ti⋯Ti separation of 2.7794 (8) Å. In the salen (N,N'-ethyl-enebis(salicyl-imine)) ligand, the two salicyl-imine units make a dihedral angle of 45.31 (5)°. The complex mol-ecules are stacked parallel to [100], forming channels in which the solvent chloro-form mol-ecules are located. C-H⋯O hydrogen-bonding inter-actions between the complex mol-ecules and the solvent mol-ecules consolidate the crystal packing. |
| Starting Page | m626 |
| Ending Page | m627 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 24454050v1 |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536813029371 |
| DOI | 10.1107/s1600536813029371 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 69 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | 2-(methylamino)-5-chlorobenzophenone imine DUOXA1 gene Imines Ligands Liter per Mole per Second Mole, unit of measurement Pyschological Bonding salen |
| Content Type | Text |
| Resource Type | Article |
