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Pd-nanodot decorated MoS2 nanosheets as a highly efficient photocatalyst for the visible-light-induced Suzuki–Miyaura coupling reaction
| Content Provider | Semantic Scholar |
|---|---|
| Author | Shin, Hyeon Ho Kang, Eunmi Park, Haeli Han, Taejun Lee, Chul-Ho Lim, Dong-Kwon |
| Copyright Year | 2017 |
| Abstract | In this work, we demonstrate that the incorporation of MoS2 nanosheets with Pd nanodots is a promising way for promoting the visible-light-induced Suzuki–Miyaura C–C coupling reaction. The MoS2 nanosheets decorated with Pd nanodots showed very high photocatalytic activity. The turnover frequency for the biphenyl product was >1600 h−1 even under sunlight illumination at room temperature. Mechanistic studies show that the high catalytic activity originated from the efficient electron–hole pair generation mechanism of MoS2 under visible-light illumination instead of purely thermal effects. |
| Starting Page | 24965 |
| Ending Page | 24971 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C7TA08441B |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c7/ta/c7ta08441b/c7ta08441b1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C7TA08441B |
| Volume Number | 5 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
