NDLI: Electrochemically induced processes of formation of phosphorus acid derivatives. 4. Synthesis of trialkyl phosphates from white phosphorus

Content Provider	Semantic Scholar
Author	Budnikova, Yu. G. Kargin, Yu. M. Zaripov, I. M. Romakhin, A. S. Ignat'ev, Yu. A. Nikitin, E. Tomilov, Andrey
Copyright Year	1992
Abstract	The products of electrolysis in dipolar aprotic solvents on the background of tetraethylammonium iodide in the presence of white phosphorus are trialkyl phosphite (the primary product after splitting of all the P-P bonds in the phosphoric oligomers) and triaryl phosphate. It was found that the formation of triaryl phosphate from white phosphorus proceeds by way of electrochemical reduction of pentaaroxyphosphorane — an intermediate product of the reaction of triaryl phosphite with iodine and phenol. A strong dependence of the yields and distribution of the products on the composition of the electrolyte has been observed.
Starting Page	1585
Ending Page	1588
Page Count	4
File Format	PDF HTM / HTML
Volume Number	41
Alternate Webpage(s)	https://page-one.springer.com/pdf/preview/10.1007/BF00866579
Alternate Webpage(s)	https://doi.org/10.1007/BF00863577
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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