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Transformations of the chameleon ligand 1,10-phenanthroline-5,6-dione/diol: cis-dichlorido(1,10-phenanthroline-5,6-dione-kappa2N,N')-trans-dipyridinecobalt(II) pyridine disolvate prepared from the diol.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Desroches, Cédric Ohrström, Lars |
| Copyright Year | 2007 |
| Abstract | The title compound, [CoCl2(C(5)H(5)N)2(C(12)H(6)N(2)O(2))].2C(5)H(5)N, is a neutral Co(II) complex with two chloride anions coordinated in a cis fashion, two pyridine ligands in trans positions and a chelating 1,10-phenanthroline-5,6-dione ligand that completes the octahedral coordination geometry. Two pyridine solvent molecules reside in channels (about 7 x 4 A wide; the closest atom-atom distance within the channel is 10 A). The three-dimensional structure supporting these channels is held together by C-H...Cl [3.466 (8)-3.670 (9) A] and C-H...O [3.014 (9)-3.285 (8) A] hydrogen bonds, and can be viewed as a CsCl or bcu (body-centred cubic) net. |
| Starting Page | 2184 |
| Ending Page | 2184 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S0108270107010554 |
| PubMed reference number | 17478897 |
| Journal | Medline |
| Volume Number | 63 |
| Part | 5 |
| Alternate Webpage(s) | http://journals.iucr.org/c/issues/2007/05/00/su3002/su3002.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S0108270107010554 |
| Journal | Acta crystallographica. Section C, Crystal structure communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
