Advances in the Engineering of Near Infrared Emitting Liquid Crystals and Copolymers , Extended Porous Frameworks , Theranostic Tools and Molecular Junctions Using Tailored Re 6 Cluster Building Blocks

Content Provider	Semantic Scholar
Author	Cordier, Stéphane Molard, Yann Brylev, Konstantin A. Mironov, Yuri V. Grasset, Fabien Fabre, Bruno Naumov, Nikolay G.
Copyright Year	2017
Abstract	At the occasion of the fiftieth birthday of the introduction of the term ‘metal atom cluster’ by F. A. Cotton in inorganic chemistry, it is the good time to make a review on the advances in the engineering of molecular assemblies and nanomaterials based on octahedral Re6 metal atom clusters. The latter exhibit unique intrinsic structural and physicochemical properties (orthogonal disposition of metallic sites that can be selectively functionalized, photoluminescence, redox, generation of singlet oxygen) that make them relevant building blocks for the structuration at the nanometric scale and functionalization of hybrid organic-inorganic materials and supramolecular frameworks. After synthesis by solid state chemistry techniques at high temperature, inorganic precursors built up on face-capped [(Re6Y8)Y6] cluster units (Y = chalcogen and/or halogen) can be functionalized via solution chemistry techniques or organic melts to form [(Re6Y8)L6] (L = CN, OH, various organic ligands...). This work reports advances in the synthesis of [(Re6Y8)Y6] and [(Re6Y8)L6] cluster units as well as on their use in the elaboration of supramolecular frameworks, nanoparticles, hybrid nanomaterials (co-polymers and liquid crystals) and active molecular junctions.
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://hal.archives-ouvertes.fr/hal-01067882/document
Language	English
Access Restriction	Open
Subject Keyword	Atom (standard) Chemistry, Inorganic Computer cluster Fever Halogens Ligands Liquid Crystals Molecular orbital Nanostructured Materials National Nanotechnology Initiative Project Component Area 2 Perrin number Photoluminescence Platform for Internet Content Selection Polymer Procedure disposition:Finding:Point in time:^Patient:Narrative Pyschological Bonding Singlet Oxygen Singlet state Solid-state chemistry Solid-state drive Transition Elements rhenium
Content Type	Text
Resource Type	Article