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A novel three-dimensional copper(II) coordination polymer with 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene and thiocyanate.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Peng, Yan-Fen Liu, Xun-Gao Li, Bao-Zong Li, Bao-Long Zhang, Yong |
| Copyright Year | 2005 |
| Abstract | In the title complex, poly[copper(II)-di-2-thiocyanato-2-1,4-bis(1,2,4-triazol-1-ylmethyl)benzene], [Cu(NCS)2(C12H12N6)]n, the CuII atom lies on an inversion centre in a tetragonally distorted octahedral environment. Four N atoms from thiocyanate and 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (bbtz) ligands fill the equatorial positions, and S atoms from symmetry-related thiocyanate ligands fill the axial positions. The benzene ring of the bbtz ligand lies about an inversion centre. Single thiocyanate bridges link the CuII atoms into two-dimensional sheets containing an unprecedented 16-membered [Cu4(-NCS-N:S)4] ring. The bbtz ligands further link the two-dimensional sheets into a three-dimensional network. |
| Starting Page | 583 |
| Ending Page | 609 |
| Page Count | 27 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S0108270105016057 |
| PubMed reference number | 15997056 |
| Journal | Medline |
| Volume Number | 61 |
| Part | 7 |
| Alternate Webpage(s) | http://journals.iucr.org/c/issues/2005/07/00/ga1092/ga1092.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S0108270105016057 |
| Journal | Acta crystallographica. Section C, Crystal structure communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
