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An Efficient System For the Pd-Catalyzed Cross-Coupling of Amides and Aryl Chlorides.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Fors, Brett P. Dooleweerdt, Karin Zeng, Qingle Buchwald, Stephen L. |
| Copyright Year | 2009 |
| Abstract | A catalyst based on a new biarylphosphine ligand (3) for the Pd-catalyzed cross-coupling reactions of amides and aryl chlorides is described. This system shows the highest turnover frequencies reported to date for these reactions, especially for aryl chloride substrates bearing an ortho substituent. An array of amides and aryl chlorides were successfully reacted in good to excellent yields. |
| Starting Page | 6576 |
| Ending Page | 6583 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://dspace.mit.edu/openaccess-disseminate/1721.1/99484 |
| Alternate Webpage(s) | http://dspace.mit.edu/bitstream/handle/1721.1/99484/Buchwald_An%20efficient%20system.pdf;jsessionid=48213F0F34133C33228F99CC9F6F3E19?sequence=1 |
| PubMed reference number | 20740063v1 |
| Volume Number | 65 |
| Issue Number | 33 |
| Journal | Tetrahedron |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Amides Aryl Hydrocarbon Hydroxylases BENZALKONIUM CHLORIDE 1 g in 59 g TOPICAL GEL [Berry Scented Hand Sanitizer] Chloride Ion Chlorides Ligands Parkinson Disease |
| Content Type | Text |
| Resource Type | Article |
