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Carbazole-based gold(I) complexes with alkyl chains of different lengths: tunable solid-state fluorescence, aggregation-induced emission (AIE), and reversible mechanochromism characteristics
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chen, Zhao Fei Yang, Lan Hu, Yuxuan Yu, Guang-Ao Liu, Sheng Hua |
| Copyright Year | 2015 |
| Abstract | In this paper, seven carbazole-based mononuclear gold(I) complexes with alkyl chains of different lengths have been synthesized and reported. All of these gold(I) complexes exhibit outstanding AIE characteristics. Furthermore, these various solid-state light-emitting AIE-active gold(I) complexes all show reversible mechanochromic fluorescent behaviors. The possible mechanism explaining these interesting AIE and mechanochromism phenomena involves a variation in weak multiple intermolecular C–H⋯F and π⋯π interactions and the formation or alteration of aurophilic interactions. |
| Starting Page | 93757 |
| Ending Page | 93764 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5RA19378H |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/ra/c5ra19378h/c5ra19378h1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5RA19378H |
| Volume Number | 5 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
