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Synthesis and structural studies of bridgehead dienes. 3 - oxobicyclo[6.3.1]dodeca -1(11),8(9) - diene - (zz) -11- carboxylic acid and 3 - oxobicyclo[7.3.1]trideca -1(12),9(10) - diene - (zz) - 12 - carboxylic acid
| Content Provider | Semantic Scholar |
|---|---|
| Author | Shea, Kenneth J. Burke, Laurence D. Doedens, Robert J. |
| Copyright Year | 1986 |
| Abstract | Abstract Single crystal X-ray structures of two bridgehead dienes are reported. The bridgehead double bonds of diene 7 show only modest deviation from strain-free tetrasubstituted double bonds. The double bonds in bridgehead diene 6, however, exhibit an average deviation of the C—CC—C torsion angle (φ + χ) of 14°. |
| Starting Page | 1841 |
| Ending Page | 1844 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/S0040-4020(01)87603-1 |
| Volume Number | 42 |
| Alternate Webpage(s) | https://cloudfront.escholarship.org/dist/prd/content/qt7qm9w1vk/qt7qm9w1vk.pdf?t=nt1bxa |
| Alternate Webpage(s) | https://doi.org/10.1016/S0040-4020%2801%2987603-1 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |