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Asymmetric hydrogenation of α- or β-acyloxy α,β-unsaturated phosphonates catalyzed by a Rh(I) complex of monodentate phosphoramidite.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Jinzhu Dong, Kaiwu Wang, Zheng Ding, Kuiling |
| Copyright Year | 2012 |
| Abstract | The Rh(I) complex of a monodentate phosphoramidite bearing a primary amine moiety (DpenPhos) has been disclosed to be highly efficient for the asymmetric hydrogenation of a variety of α- or β-acyloxy α,β-unsaturated phosphonates, providing the corresponding biologically important chiral α- or β-hydroxy phosphonic acid derivatives with excellent enantioselectivities (90->99% ee). |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c1ob06835k |
| PubMed reference number | 22218565 |
| Journal | Medline |
| Volume Number | 10 |
| Issue Number | 8 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ob/c1/c1ob06835k/c1ob06835k.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c1ob06835k |
| Journal | Organic & biomolecular chemistry |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |