Loading...
Please wait, while we are loading the content...
Activation of H2 over the Ru-Zn Bond in the Transition Metal-Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt](.).
| Content Provider | Semantic Scholar |
|---|---|
| Author | Riddlestone, Ian Rajabi, Nasir Ahmad Lowe, John P. Mahon, Mary F. T. Macgregor, Stuart A. Whittlesey, Michael K. |
| Copyright Year | 2016 |
| Abstract | Reaction of [Ru(IPr)2(CO)H]BAr(F)4 with ZnEt2 forms the heterobimetallic species [Ru(IPr)2(CO)ZnEt]BAr(F)4 (2), which features an unsupported Ru-Zn bond. 2 reacts with H2 to give [Ru(IPr)2(CO)(η(2)-H2)(H)2ZnEt]BAr(F)4 (3) and [Ru(IPr)2(CO)(H)2ZnEt]BAr(F)4 (4). DFT calculations indicate that H2 activation at 2 proceeds via oxidative cleavage at Ru with concomitant hydride transfer to Zn. 2 can also activate hydridic E-H bonds (E = B, Si), and computed mechanisms for the facile H/H exchange processes observed in 3 and 4 are presented. |
| File Format | PDF HTM / HTML |
| DOI | 10.1021/jacs.6b05243 |
| PubMed reference number | 27490786 |
| Journal | Medline |
| Volume Number | 138 |
| Issue Number | 35 |
| Alternate Webpage(s) | http://opus.bath.ac.uk/51515/1/Whittlesey_revised_manuscript.pdf |
| Alternate Webpage(s) | https://purehost.bath.ac.uk/ws/portalfiles/portal/147466253/Whittlesey_revised_manuscript.pdf |
| Alternate Webpage(s) | https://pureapps2.hw.ac.uk/ws/portalfiles/portal/16600823/Zn_H_JACS_final_accepted.pdf |
| Alternate Webpage(s) | https://doi.org/10.1021/jacs.6b05243 |
| Journal | Journal of the American Chemical Society |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
