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Solvothermal in situ metal/ligand reactions: a new bridge between coordination chemistry and organic synthetic chemistry.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chen, Xiao-Ming Tong, Ming-Liang |
| Copyright Year | 2007 |
| Abstract | Several important solvothermal (including hydrothermal) in situ metal/ligand reactions and their mechanisms, including dehydrogenative carbon-carbon coupling, hydroxylation of aromatic rings, cycloaddition of organic nitriles with azide and ammonia, transformation of inorganic and organic sulfur, as well as the CuII to CuI reduction, are outlined in this Account. The current progress clearly demonstrates the important potential of such reactions in the crystal engineering of functional coordination compounds and one-pot synthesis of some unusual organic ligands that are inaccessible or not easily obtainable via conventional methods, thereby substantiating our expectation that a new bridge has been created between coordination chemistry and synthetic organic chemistry. |
| Starting Page | 3382 |
| Ending Page | 3387 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://or.nsfc.gov.cn/bitstream/00001903-5/17881/1/1000000898350.pdf |
| PubMed reference number | 17309196v1 |
| Volume Number | 40 |
| Issue Number | 2 |
| Journal | Accounts of chemical research |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | AROMATICS Ammonia Azides Chemistry, Organic Hydroxylation Ligands Marijuana Abuse Nitriles Ring device Synthesis Chemistry Technetium Tc 99m Sulfur Colloid |
| Content Type | Text |
| Resource Type | Article |
