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Polypseudorotaxane architecture of poly-bis[4-(N-benzyl- pyridinium)]piperazine-hexa-thiocyanato-di-cadmium(II) with 2-D honeycomb-like [Cd(SCN)3]nn− anionic polymeric framework
| Content Provider | Semantic Scholar |
|---|---|
| Author | Lai, Long-Li Wu, Chun-Han Lu, Kuang-Lieh Wen, Yu‐ Shen Liu, Yi-Hung Wang, Yu Cheng, Kung‐ Lung Soldatov, Dmitriy V. |
| Copyright Year | 2007 |
| Abstract | An unusual, honeycomb-like cadmium-tri-thiocyanate polymeric framework was found in the studied hybrid material of general formula (L2+)n[Cd(SCN)3]2n2n− (3), where L2+ is bis[4-(N-benzylpyridinium)]piperazine dication. The perforated coordination net forms due to a template effect of the organic dications which reside in the holes penetrating the net in a polyrotaxane-like manner. The salt (L2+)(SCN)2·2H2O (4) was studied for comparison. |
| Starting Page | 345 |
| Ending Page | 349 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/B701229B |
| Volume Number | 9 |
| Alternate Webpage(s) | http://ntur.lib.ntu.edu.tw//bitstream/246246/169720/1/183.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/B701229B |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
