NDLI: Asymmetric Synthesis of Tri- and Tetrasubstituted Trifluoromethyl Dihydropyranones from α-Aroyloxyaldehydes via NHC Redox Catalysis

Content Provider	Semantic Scholar
Author	Davies, Alyn T. Pickett, Philip M. Slawin, Alexandra M. Z. Smith, Andrew D.
Copyright Year	2014
Abstract	The asymmetric synthesis of tri- and tetrasubstituted trifluoromethyl dihydropyranones via an NHC-catalyzed redox process, introducing methyl, benzyl, and aryl substituents to the C(5) position, is presented. Their substrate-controlled derivatization into δ-lactones and cyclic hemiacetals containing stereogenic trifluoromethyl groups is also described.
Starting Page	2696
Ending Page	2700
Page Count	5
File Format	PDF HTM / HTML
DOI	10.1021/cs500667g
Volume Number	4
Alternate Webpage(s)	https://research-repository.st-andrews.ac.uk/bitstream/handle/10023/6984/Smith_2014_ACSC_Asymmetric_AM.pdf?isAllowed=y&sequence=1
Alternate Webpage(s)	https://doi.org/10.1021/cs500667g
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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