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[C16MPy]AlCl3Br: an efficient novel ionic liquid for synthesis of novel 1,2,4-triazolidine-3-thiones in water
| Content Provider | Semantic Scholar |
|---|---|
| Author | Patil, Jayavant D. Pore, Dattaprasad M. |
| Copyright Year | 2014 |
| Abstract | An efficient novel ionic liquid, [C16MPy]AlCl3Br has been synthesized and explored as a catalyst for an eco-friendly synthesis of novel 1,2,4-triazolidine-3-thiones in water at ambient temperature. A variety of aldehydes undergo smooth reaction with thiosemicarbazide and substituted thiosemicarbazides. In the case of substituted thiosemicarbazides the corresponding 1,2,4-triazolidine-3-thiones are obtained as products instead of 1,3,4-oxadiazoles. A broad variety of functional groups are tolerated and a large number of substrates can be applied with this protocol. Rapid eco-friendly reactions with high yields, use of ambient temperature and water as a solvent, easy work-up procedure as well as isolation of product, excellent catalyst recyclability, high atom economy, novelty of ionic liquid as well as the protocol are the auxiliary advantages of the protocol. |
| Starting Page | 14314 |
| Ending Page | 14319 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C3RA46916F |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ra/c3/c3ra46916f/c3ra46916f1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C3RA46916F |
| Volume Number | 4 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
