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Synthesis, Spectroscopy and Electrochemistry of nitroso terpyridine-{1-(alkyl)-2-(arylazo) imidazole}ruthenium(II) Complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Byabartta, Prithwiraj |
| Copyright Year | 2014 |
| Abstract | Silver assisted aquation of blue [RuCl(tpy)(RaaiR ´ )](ClO 4 ) ( 1a-1i ) leads to the synthesis of solvento species, blue-violet [Ru(OH 2 )(tpy)(RaaiR ´ )](ClO 4 )( 2a-2i ), [RaaiR ´ =p-R-C 6 H 5 -N=N-C 3 H 2 -NN, abbreviated as N,N / -chelator, R = Me, Et, Bz, p-R=H Me, Cl] that have been reacted with NaNO 2 in warm EtOH resulting in violet nitro complexes of the type, [Ru(NO 2 )(tpy)(RaaiR)](ClO 4 )( 3a-3i ). The nitrite complexes are useful synthons of electrophilic nitrosyls, and on triturating the nitro compounds with conc. HClO 4 nitrosyl derivatives, [Ru(NO)(tpy)(RaaiR)](ClO 4 ) 3 are isolated. The diazotization of the primary aromatic amines with a strongly electrophilic mononitrosyl complex in acetonotrile and dichloromethane solution was thoroughly studied. |
| Starting Page | 1 |
| Ending Page | 14 |
| Page Count | 14 |
| File Format | PDF HTM / HTML |
| Volume Number | 1 |
| Alternate Webpage(s) | http://www.journals.wsrpublishing.com/index.php/tjasr/article/download/9/278 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |