NDLI: The spectroscopy and thermochemistry of phenylallyl radical chromophores

Content Provider	Semantic Scholar
Author	Troy, Tyler P. Chalyavi, Nahid Menon, Ambili S. O'Connor, Gerard D. Fückel, Burkhard Nauta, Klaas Radom, Leo Schmidt, Timothy W.
Copyright Year	2011
Abstract	The resonant two-color two-photon ionization and laser induced fluorescence excitation spectra of the 1-phenylallyl (cinnamyl) and inden-2-ylmethyl radicals are reported. The 1-phenylallyl radical is found to fluoresce with low yield, permitting only a coarse dispersed fluorescence spectrum, while the inden-2-ylmethyl radical yields sufficient fluorescence to obtain ground-state vibrational frequencies and two-dimensional fluorescence spectra. Computed ionization energies and thermochemical properties including radical stabilization energies are reported for a range of resonance-stabilized radicals, including the phenylpropargyl, vinylpropargyl and phenylallyl radicals.
Starting Page	1755
Ending Page	1765
Page Count	11
File Format	PDF HTM / HTML
DOI	10.1039/C1SC00247C
Volume Number	2
Alternate Webpage(s)	http://doc.rero.ch/record/25007/files/troi_stp.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C1SC00247C
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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