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Pyridine-decorated carbon nanotubes as a metal-free heterogeneous catalyst for mild CO2 reduction to methanol with hydroboranes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Tuci, Giulia Rossin, Andrea Luconi, L. Huu, Cuong Pham‐ Cicchi, Stefano Ba, Houleymata Giambastiani, Giuliano |
| Copyright Year | 2017 |
| Abstract | Pyridine decorated multi-walled carbon nanotubes (NPy-MW) have been successfully employed as a catalyst for the reduction of carbon dioxide to methyl borinate (R2BO–CH3) in the presence of 9-borabicyclo[3.3.1]nonane. NPy-MW represents the first example of a heterogeneous, metal-free and durable catalyst for CO2 hydroboration to methanol. A mechanistic cycle has been proposed on the basis of targeted blank experiments and a quantum chemical study, highlighting the non-innocent role played by the nanotube carrier in the final NPy-MW catalytic performance. |
| Starting Page | 5833 |
| Ending Page | 5837 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C7CY01772C |
| Volume Number | 7 |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2017/cy/c7cy01772c |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c7/cy/c7cy01772c/c7cy01772c1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C7CY01772C |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
