F-TiO2/P(VDF-HFP) hybrid films with enhanced dielectric permittivity and low dielectric loss

Content Provider	Semantic Scholar
Author	Yu, Enjie Zhang, Qilong Xu, Nuoxin Yang, H.
Copyright Year	2017
Abstract	In this study, self-assembly flower-like TiO2 (F-TiO2) particles with an average diameter of 400 nm are synthesized via a facile one-pot solvothermal method. P(VDF-HFP)-based composites with F-TiO2 particles of different volume ratio as fillers are prepared. Microstructure and thermal analyses confirm that F-TiO2 does not change the crystallization process of the polymer matrix, but disrupts the crystallization degree of P(VDF-HFP). Dielectric properties measured at various frequencies and temperatures indicate that the addition of the F-TiO2 fillers enhances the dielectric constant of the composites, while the dielectric loss and electric conductivity do not significantly increase. The dielectric permittivity of the polymer nanocomposites is enhanced by 200% over that of the P(VDF-HFP) matrix at a filler content of 20 vol% while maintaining a rather low dielectric loss (0.043 at 1 kHz). Especially, the F-TiO2/P(VDF-HFP) composites exhibit low electric conductivity (≤10−11 S cm−1) at low frequencies. All the improved performances suggest an easy method to fabricate nanocomposites having potential electrical applications.
Starting Page	3949
Ending Page	3957
Page Count	9
File Format	PDF HTM / HTML
DOI	10.1039/C6RA26772F
Volume Number	7
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2017/ra/c6ra26772f
Alternate Webpage(s)	https://doi.org/10.1039/C6RA26772F
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article