NDLI: Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap

Please wait, while we are loading the content...

Electrochemical film deposition of the zirconium metal-organic framework uio-66 and application in a miniaturized sorbent trap

Content Provider	Semantic Scholar
Author	Stassen, Ivo Styles, Mark J. Assche, Tom R. C. Van Campagnol, Nicolò Fransaer, Jan Denayer, Joeri F. M. Tan, Jin-Chong Falcaro, Paolo Vos, Dirk E. De Ameloot, Rob
Copyright Year	2015
Abstract	Film deposition is an enabling technology for integration of novel functional materials into real-world practical applications. We report both the anodic and cathodic electrochemical film deposition of UiO-66, a prototype of highly stable, zirconium-based metal–organic frameworks, using zirconium foil as the only metal source. The fundamentally different film formation mechanisms at the cathode and anode result in a significantly different coating adhesion strength, mainly due to the formation of an oxide film serving as a bridging layer at the anode. The patterned deposition capability of the electrochemical method enables the straightforward integration of UiO-66 as a sorbent film in a miniaturized sorbent trap for online analytical sampling and concentration of dilute volatile organic compounds.
Starting Page	1801
Ending Page	1807
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1021/cm504806p
Volume Number	27
Alternate Webpage(s)	http://www.eng.ox.ac.uk/tan/pdf-publications/StassenChemMater2015.pdf
Alternate Webpage(s)	http://www2.eng.ox.ac.uk/tan/pdf-publications/Stassen_ChemMater_2015_SI.pdf
Alternate Webpage(s)	https://doi.org/10.1021/cm504806p
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in