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Bis(μ-diisopropylhydoxylaminato)-κ2 O:N;κ2 O:O-bis[(diisopropylhydoxylaminato-κO)beryllium]
| Content Provider | Semantic Scholar |
|---|---|
| Author | Berger, Raphael J. F. Jana, Surajit Monkowius, Uwe Mitzel, Norbert W. |
| Copyright Year | 2012 |
| Abstract | The title compound, [Be2(C6H14NO)4], was prepared from a solution of BeCl2 in diethyl ether and two equivalents of O-lithia-ted N,N-diisopropyl-hydoxyl-amine. The mol-ecular structure is composed of a dinuclear unit forming a central five-membered planar Be-O-Be-O-N ring (sum of inter-nal angles = 540.0°; r.m.s. deviation from planarity = 0.0087 Å). Both Be atoms show the unusual coordination number of three, with one Be atom coordinated by three O atoms and the other by two O atoms and one N atom, both in distorted trigonal-planar environments. The Be-O distances are in the range 1.493 (5)-1.600 (5) Å and the Be-N distance is 1.741 (5) Å. |
| Starting Page | m1463 |
| Ending Page | m1463 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 23468690 |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536812045655 |
| DOI | 10.1107/S1600536812045655 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 68 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Amine Oxidase (Copper-Containing) Amines Distance Equivalent Weight ethyl ether |
| Content Type | Text |
| Resource Type | Article |
