NDLI: Enzymatic kinetic resolution of primary allenic alcohols. Application to the total synthesis and stereochemical assignment of striatisporolide A.

Content Provider	Semantic Scholar
Author	Deska, Jan Bäckvall, Jan-E
Copyright Year	2009
Abstract	Crude Porcine pancreatic lipase was successfully used for the kinetic resolution of axially chiral primary allenic alcohols providing very high enantioselectivities with E values above 200. This simple access to optically active allenes was applied to the total synthesis of the fungal metabolite (-)-striatisporolide A, allowing its unambiguous stereochemical assignment.
File Format	PDF HTM / HTML
DOI	10.1039/b912128p
PubMed reference number	19675888
Journal	Medline
Volume Number	7
Issue Number	17
Alternate Webpage(s)	http://www.rsc.org/suppdata/ob/b9/b912128p/b912128p.pdf
Alternate Webpage(s)	https://doi.org/10.1039/b912128p
Journal	Organic & biomolecular chemistry
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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