NDLI: Electrooxidation of alcohols catalyzed by amino alcohol ligated ruthenium complexes.

Content Provider	Semantic Scholar
Author	Brownell, Kristen R. McCrory, Charles C. L. Chidsey, Christopher E. D. Perry, Richard H. Zare, Richard N. Waymouth, Robert M.
Copyright Year	2013
Abstract	Ruthenium transfer hydrogenation catalysts physisorbed onto edge-plane graphite electrodes are active electrocatalysts for the oxidation of alcohols. Electrooxidation of CH3OH (1.23 M) in a buffered aqueous solution at pH 11.5 with [(η(6)-p-cymene)(η(2)-N,O-(1R,2S)-cis-1-amino-2-indanol)]Ru(II)Cl (2) on edge-plane graphite exhibits an onset current at 560 mV vs NHE. Koutecky-Levich analysis at 750 mV reveals a four-electron oxidation of methanol with a rate of 1.35 M(-1) s(-1). Mechanistic investigations by (1)H NMR, cyclic voltammetry, and desorption electrospray ionization mass spectrometry indicate that the electroxidation of methanol to generate formate is mediated by surface-supported Ru-oxo complexes.
File Format	PDF HTM / HTML
DOI	10.1021/ja4055564
PubMed reference number	24044700
Journal	Medline
Volume Number	135
Issue Number	38
Alternate Webpage(s)	http://web.stanford.edu/group/Zarelab/publinks/890.pdf
Alternate Webpage(s)	https://doi.org/10.1021/ja4055564
Journal	Journal of the American Chemical Society
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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